(2Z)-N-(2-Chlorobenzyl)-2-(2-oxo-2,3- dihydro-1H-indol-3-ylidene)hydrazine carbothioamide

Please use this identifier to cite or link to this item: http://digitalrepository.fccollege.edu.pk/handle/123456789/2232

Title:	(2Z)-N-(2-Chlorobenzyl)-2-(2-oxo-2,3- dihydro-1H-indol-3-ylidene)hydrazine carbothioamide
Authors:	Pervez, Humayun Khan, Nazia Iqbal, Mohammad S. Yaqub, Muhammad Tahir, M. Nawaz
Keywords:	single-crystal X-ray study; T = 296 K; mean (C–C) = 0.003 A˚; R factor = 0.043; wR factor = 0.105; data-to-parameter ratio = 18.9
Issue Date:	8-Aug-2012
Publisher:	Acta Crystallographica Section E: Structure Reports Online
Citation:	Pervez, Humayun, et al. "(2Z)-N-(2-Chlorobenzyl)-2-(2-oxo-2, 3-dihydro-1H-indol-3-ylidene) hydrazinecarbothioamide." Acta Crystallographica Section E: Structure Reports Online 68.9 (2012): o2731-o2731.
Abstract:	In the title compound, C16H13ClN4OS, the isatin ring system is oriented at dihedral angles of 10.60 (7) and 72.60 (3) with respect to the thiosemicarbazide and 2-chlorobenzyl groups, respectively. The near planarity of the isatin and thio semicarbazide groups [r.m.s. deviations of 0.0420 and 0.0163 A˚ , respectively] is reinforced by intramolecular N— H O and N—H N hydrogen bonds, which generate S(6) and S(5) rings, respectively. In the crystal, inversion dimers linked by pairs of N—H O hydrogen bonds generate R2 2 (8) loops. Aromatic – stacking interactions between the centroids of heterocyclic five-membered and benzene rings [distance = 3.6866 (11) A˚ ] are also observed
URI:	http://202.142.177.21/handle/123456789/2232
Appears in Collections:	Chemistry Department

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